Ball clay
is an
extremely rare
mineral found in very few places around the world.
The blue clays of the Bagshot beds found around Wareham are of the finest
in the world. The main
concentration of ball clay in Dorset is to the north of the Purbeck Hills centered
around Norden. The term "Ball Clay is applied to those plastic
"transported" clays which when fired in an oxidising atmosphere to
the temperature of certain pottery ovens- approx 1150°-1200°C have a white
or nearly white colour. Its name dates back to the early methods of
mining when specialised hand tools were used to extract the clay in rough cube
shapes of about 30 cm. As the corners were knocked
through handling and storage these cubes became rounded and ‘ball’
shaped. Like many other clays, Ball Clays are formed by the decomposition of
felspathic rocks by natural agencies. In this decomposition silicates such as
the felsphars break down, and the products ultimately undergo hydration with
the formation of of the hydrated silicate of aluminum, kaolinite, and in many
cases mixtures of hydrated oxides. Where these products are found resting in
the parent rock, the clays are call residual; where they have been transported
and deposited elsewhere, they are known as transported clays. The China clays
of Cornwall are typical examples of residual clays and the ball clays of Devon
and Dorset examples of transported clays. The two types differ in one
important respect; the residual clay contains un-decomposed constituents of
the parent rock; for example, in the case of china clay, the quartz and the
mica; the transported clay, on the other hand has undergone a variable amount
of natural 'sorting'. All this took place approximately 45 million years ago in tropical times.
An ancient river
Solent washed Kaolinite from its parent
rock on Dartmoor. (At this time the Isle
of Wight was still joined to Purbeck.) As the streams flowed from upland
areas the mixed with other clay minerals, sands, gravels and vegetation before
settling in low-lying basins to form overlaying seams of ball clay.
Ball clays contain
three dominant minerals: from 20-80% Kaolinite, 10-25% mica, and 6-65% quartz.
In addition, there are other 'accessory' minerals and some carbonaceous
material (derived from ancient plants) present.
The wide variation both in mineral composition and in the size of the
clay particles results in different characteristics for individual clay seams
within a deposit.
Purbeck Ball clay has been used for thousands of years but large scale commercial extraction began in the middle of the 18th Century continuing to the present day with open cast workings at Povington, Arne and North of Wareham. Before the rise of Poole, Wareham was the port for the area, and 32,000 tons of cargo were recorded shipped from the quay in the 1860's.
This view shows the old clay warehouse in Wareham from which ball clay was loaded on to ships. This building is now situated in the grounds of "The Priory" hotel.
The British Geological Survey describes ball clay as ‘relatively scarce globally’, and hence of importance to the UK’s economy. In 2002, UK ball clay was an essential ingredient of 50% of the world's production of sanitaryware. Within the UK, ball clay occurs commercially only in the Wareham Basin of Purbeck and within two areas of Devon. Nowadays it is used primarily in the ceramics industry for the production of wall and floor tiles (about three quarters of output), tableware, sanitary ware and electrical insulators. It is also used as a filler in certain rubber and plastic products such as windscreen wipers, and garden hoses. Over the four years prior to 2009, the production of ball clay in Dorset fluctuated around 250,000 tonnes per annum (tpa), although in 2008-2009 this fell to 150,000 tpa due largely to the global economic recession. Since then there are signs of recovery. Click Here to read an account of life
for the clay workers and others in Purbeck
written in 1885 (year of the opening of the Railway) for the American Journal
"Harpers New Monthly Magazine". Extraction methods have constantly evolved. From an early date a specially shaped spade - or tubal - was developed, which was eventually superseded by the pneumatic spade. The clay has been quarried and mined. When mined the use of shaft mines and adits was common place in Purbeck as conditions dictated. Initially the extracted clay was weathered, a manual process that required it to be spread across large "beds" in the open. In later years it was found that this process could be speeded up artificially by shredding. Individual raw clay selections are blended carefully according to pre-determined recipes to provide a product with a consistent and predictable range of characteristics and behaviour. The first stage in processing then is to shred (or ‘kibble’) the blended clay into smaller, more regular lumps about the size of a golf ball. Much blended clay is sold in this shredded form. Further processing through drying and grinding yields powdered plastic clays and ceramics manufacturers (particularly in the sanitaryware sector) also have benefited from the development of refined ball clays which offer improved performance and reduced manufacturing process costs. Refined clays are available in ‘noodled’ and slurried form. Ball clays also are sold in a partially dried form, which consist of golf ball size materials that are not powdered. . A vital material in ceramics - Ball clays are used in many different industries, but in particular form a vital component in ceramic manufacturing. Kaolin (‘china clay’) produces a very white colour when it is fired, but used alone it is brittle and weak and must be mixed with ball clay to produce a workable, malleable raw material. As a result of their sedimentary origin, raw ball clays have a wide range of colours. However, many of them are valued by the ceramics industry for their white-firing properties, which are determined by the levels of iron and other colouring/fluxing oxides within the clay.
Ball Clay Uses
Sanitaryware:
A ‘ceramic body’ for sanitary ware typically includes 30% ball clay to
provide plasticity and workability, 20% kaolin, 30% feldspar and 20%
quartz/silica.
Tableware:
Ceramic tableware utilizes ball clay to provide high plasticity and a good
white-fired colour, combined with kaolin, feldspar and quartz.
Wall and floor tiles:
Combined with talc, feldspar, quartz/silica and kaolin, ball clays are
utilized for their plasticity and bonding properties.
Glazes and engobes:
Ball clays are also used in the production of coatings for ceramic products
to ensure the perfect finish.
Refractory clays:
An ability to resist the effects of extremely high temperatures makes ball
clay ideal for use in refractory products such as kiln insulation and kiln furniture.
Construction
ceramics: Building materials such as bricks, clay pipes and roof tiles all contain
ball clay.
Electrical porcelain
insulators: You will find ball clays in the electrical porcelain components that
provide insulation from high voltage currents.
Non-ceramic
applications:
These include the
construction industry; horticulture, agriculture, pharmaceutical and amenity
industries; use as fillers and extenders in polymers, adhesives, plastics,
sealants, medicines, fertilizers
and insecticides.
|
|